Sulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins
DALTON TRANSACTIONS, cilt.43, sa.48, ss.17916-17919, 2014 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 43 Sayı: 48
- Basım Tarihi: 2014
- Doi Numarası: 10.1039/c4dt02412e
- Dergi Adı: DALTON TRANSACTIONS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.17916-17919
- Acıbadem Mehmet Ali Aydınlar Üniversitesi Adresli: Hayır
Özet
4-tert-Butylbenzenesulfonamide was used as a substituent of tetra peripherally substituted Fe(II) phthalocyanine, taking into account several parameters crucial for the design of potential oxidation catalysts such as solubility and stability. The resulting phthalocyanine exhibits a remarkable stability under oxidative conditions. The main product of the oxidation of cyclohexene using H2O2 as the oxidant is the allylic ketone, 2-cyclohexen-1-one. Styrene oxidation led mainly to the formation of benzaldehyde.