Sulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins

Isci U., Caner C., Zorlu Y., Gurek A. G. , DUMOULIN F. , Ahsen V.

DALTON TRANSACTIONS, cilt.43, ss.17916-17919, 2014 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 43 Konu: 48
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1039/c4dt02412e
  • Sayfa Sayıları: ss.17916-17919


4-tert-Butylbenzenesulfonamide was used as a substituent of tetra peripherally substituted Fe(II) phthalocyanine, taking into account several parameters crucial for the design of potential oxidation catalysts such as solubility and stability. The resulting phthalocyanine exhibits a remarkable stability under oxidative conditions. The main product of the oxidation of cyclohexene using H2O2 as the oxidant is the allylic ketone, 2-cyclohexen-1-one. Styrene oxidation led mainly to the formation of benzaldehyde.