Sulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins
DALTON TRANSACTIONS, vol.43, no.48, pp.17916-17919, 2014 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 43 Issue: 48
- Publication Date: 2014
- Doi Number: 10.1039/c4dt02412e
- Journal Name: DALTON TRANSACTIONS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.17916-17919
- Acibadem Mehmet Ali Aydinlar University Affiliated: No
Abstract
4-tert-Butylbenzenesulfonamide was used as a substituent of tetra peripherally substituted Fe(II) phthalocyanine, taking into account several parameters crucial for the design of potential oxidation catalysts such as solubility and stability. The resulting phthalocyanine exhibits a remarkable stability under oxidative conditions. The main product of the oxidation of cyclohexene using H2O2 as the oxidant is the allylic ketone, 2-cyclohexen-1-one. Styrene oxidation led mainly to the formation of benzaldehyde.