Subtle variations of the behavior of a silylated tetraethylene glycol-substituted Zn phthalocyanine towards acids


Onal E., Topal S. Z. , Tarhouni M., Isci U., Bassem J., Ahsen V., ...Daha Fazla

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, cilt.20, ss.1182-1189, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 20
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1142/s1088424616500371
  • Dergi Adı: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
  • Sayfa Sayıları: ss.1182-1189

Özet

An organosoluble phthalocyanine substituted by four silylated tetraethyleneglycol chains was designed. This phthalocyanine become water-soluble after acid-promoted removal of the TBDMS moieties (which does not occur in acetonitrile), and is therefore a naked-eye observation system of acid aqueous media. Fluoride anion sensitivity based on the same principle proved unfortunately unsuccessful.