Bis[-4,5-dicyano-N,N′-bis-(p-tolyl-sulfon-yl)-o-phenyl-enediaminato] bis-[diamminecopper(II)] dihydrate

Yuksel, Fatma; Tuncel, SİNEM; Gürek, Aye; Jeanneau, Erwann; Luneau, Dominique; Ahsen, Vefa

doi:10.1107/s1600536807017643

Bis[-4,5-dicyano-N,N′-bis-(p-tolyl-sulfon-yl)-o-phenyl-enediaminato] bis-[diamminecopper(II)] dihydrate

Atıf İçin Kopyala

Yuksel F., Tuncel S., Gürek A. G., Jeanneau E., Luneau D., Ahsen V.

Acta Crystallographica Section E: Structure Reports Online, cilt.63, sa.5, 2007 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 63 Sayı: 5
Basım Tarihi: 2007
Doi Numarası: 10.1107/s1600536807017643
Dergi Adı: Acta Crystallographica Section E: Structure Reports Online
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Acıbadem Mehmet Ali Aydınlar Üniversitesi Adresli: Hayır

Özet

The title complex, [Cu2(C22H16N4O4S2)2(NH3)4]·2H2O, is a centrosymmetric dimer. The two copper ions are bridged by two 4,5-dicyano-N,N′-bis-(p-tolyl-sulfonyl)-o-phenyl-ene-di-am-ine ligands; the Cu⋯Cu distance is 8.749 (1) Å. Each copper ion is in a distorted square-pyramidal geometry, defined by two N atoms from one ligand, two N atoms from two coordinated ammonia mol-ecules and one CN from the other ligand apically. The hydrogen-bonding network leads to a layered structure. © 2007 International Union of Crystallography. All rights reserved.