Comparative structural analysis of 4,5-and 3,6-dialkylsulfanylphthalonitriles of different bulkiness

Zorlu Y., Isci U., Un I., Kumru U., DUMOULIN F., Ahsen V.

STRUCTURAL CHEMISTRY, cilt.24, sa.4, ss.1027-1038, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 24 Sayı: 4
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1007/s11224-012-0126-8
  • Dergi Adı: STRUCTURAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1027-1038
  • Anahtar Kelimeler: Phthalonitrile, Adamantanethiol, Cyclohexanethiol, Hexanethiol, Alkylsulfanylphthalonitrile, Single crystal, IR, NMR, Comparative structural analysis, NON-PERIPHERAL POSITIONS, SUBSTITUTED PHTHALOCYANINES, EMERGING APPLICATIONS, ELECTRONIC-PROPERTIES, ZINC PHTHALOCYANINES, CHEMISTRY, ANALOGS, DYES
  • Acıbadem Mehmet Ali Aydınlar Üniversitesi Adresli: Hayır

Özet

Phthalonitriles disubstituted by alkylsulfanyl moieties of different bulkiness (tert-butyl, adamantly, cyclohexyl and hexyl) and in 4,5- or 3,6-positions, respectively, set A and set B, have been prepared for comparative structural analyses. Miscellaneous parameters such as melting points and related polarity of the compounds are summarized. Substituents position and bulkiness effects on NMR and IR spectroscopy as well as refined X-ray structural data were examined.