Preparation of N-bridged diiron phthalocyanines bearing bulky or small electron-withdrawing substituents

Isci U., DUMOULIN F., Ahsen V., Sorokin A. B.

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, cilt.14, sa.4, ss.324-334, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 14 Sayı: 4
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1142/s1088424610002069
  • Dergi Adı: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.324-334
  • Anahtar Kelimeler: mu-nitrido dimer, diiron, alkylsulfonyl substituents, catalysis, IRON TETRASULFOPHTHALOCYANINE FEPCS, CATALYZED OXIDATION, SELECTIVE OXIDATION, TERT-BUTYLHYDROPEROXIDE, HETEROGENEOUS OXIDATION, AROMATIC-COMPOUNDS, HYDROGEN-PEROXIDE, COMPLEXES, ACID, OXYGEN
  • Acıbadem Mehmet Ali Aydınlar Üniversitesi Adresli: Hayır

Özet

The synthesis of novel mu-nitrido diiron phthalocyanine with electron-withdrawing substituents is reported: mu-nitrido tetra-methylsulfonylphthalocyanine (13), mu-nitrido tetra-ethylsulfonyl-phthalocyanine (14), mu-nitrido tetra-adamantylsulfonylphthalocyanine (15), mu-nitrido tetra-cyclohexyl-sulfonylphthalocyanine (16). These complexes were characterized by ESI-MS, UV-vis, FT-IR and EPR techniques. The state of these complexes depends on the size of the substituents. Complexes 13 and 14 bearing small methylsulfonyl and ethylsulfonyl substituents are cationic ((PcFeNFePc)-N-IV-Pc-IV)(+)N(3)(-)complexes while complexes 15 and 16 with bulkier adamantylsulfonyl and cyclohexylsulfonyl substituents are formally neutral (PcFeNFePc)-N-III-Pc-IV complexes which can be represented as PcFe(+3.5)NFe(+3.5)Pc.