Octasolketal-substituted phthalocyanines: synthesis and systematic study of metal effect and substitution pattern on C-13 NMR

Zorlu Y., Un I., DUMOULIN F.

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, vol.13, no.6, pp.760-768, 2009 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 13 Issue: 6
  • Publication Date: 2009
  • Doi Number: 10.1142/s1088424609000887
  • Journal Name: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.760-768
  • Keywords: solketal, C-13 NMR, octasubstitution, peripheral, non-peripheral, metal effect, SPECTRA, LIQUID, ALKYL, H-1
  • Acibadem Mehmet Ali Aydinlar University Affiliated: Yes

Abstract

A complete series of solketal octasubstituted phthalocyanines have been synthesized, with peripheral (beta) or non-peripheral (alpha) substitution pattern. Their C-13 NMR and UV-vis properties are compared relatively to this substitution pattern or the nature of the central metal (Ni, Zn or H-2).