Nano-ordered MCM-41-SO3H an efficient catalyst for the synthesis of N-substituted pyrroles in water


H. G., Emamı A., Dekamin M. G.

SCIENTIA IRANICA INTERNATIONAL JOURNAL OF SCIENCE & TECHNOLOGY, vol.23, no.3, pp.1102-1110, 2016 (SCI-Expanded) identifier

Abstract

Condensation of 2,5-dimethoxytetrahydrofuran and aniline derivatives has been carried out in aqueous media in the presence of mesoporoushydrogen sulfated MCM-41 (MCM-41-SO3H). The reaction is smoothly catalyzed by very low loading of heterogeneous MCM-41-SO3H to afford a wide variety of N-substituted pyrroles. This procedure is clean, environmentally friendly and has many advantages including short reaction time, high yields, low cost and simple work-up. The catalyst could be recycled at least 3 times without substantial decrease of its catalytic activity.