Synthesis and characterizations of peripheral octa-amino and octa-amidophthalocyanines

Yuksel F., Tuncel S., Ahsen V.

Journal of Porphyrins and Phthalocyanines, cilt.12, sa.2, ss.123-130, 2008 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 12 Sayı: 2
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1142/s1088424608000169
  • Dergi Adı: Journal of Porphyrins and Phthalocyanines
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.123-130
  • Anahtar Kelimeler: Octa-amidophthalocyanine, Octa-aminophthalocyanine, Phthalocyanine
  • Acıbadem Mehmet Ali Aydınlar Üniversitesi Adresli: Hayır

Özet

Novel 2,3,9,10,16,17,23,24-octaamino substituted Ni(II) phthalocyanine (2) was synthesized from tosylamido (tosyl: toluene-p-sulphonyl) derivative by the cleavage of tosyl groups in the presence of 90% sulfuric acid. Octa-hexanoylamido Ni(II) phthalocyanine (3a) and octa-lauroylamido Ni(II) phthalocyanine (3b) were obtained by reacting of octa-amino Ni(II) phthalocyanine (2) with hexanoyl chloride and lauroyl chloride, respectively. The new compounds have been characterized by elemental analysis, FT-IR, NMR and UV-vis spectroscopy and mass spectrometry. The aggregation behaviors of new compounds were investigated by UV-vis spectroscopy. Copyright © 2008 Society of Porphyrins & Phthalocyanines.