Resorcinarene-mono-benzimidazolium salts as NHC ligands for Suzuki-Miyaura cross-couplings catalysts

İŞCİ Ü., AYGÜN M., SEVİNÇEK R., ZORLU Y., DUMOULIN F.

TURKISH JOURNAL OF CHEMISTRY, cilt.39, sa.6, ss.1300-1310, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 39 Sayı: 6
  • Basım Tarihi: 2015
  • Doi Numarası: 10.3906/kim-1506-50
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.1300-1310
  • Anahtar Kelimeler: Suzuki-Miyaura reaction, resorcinarene, cavitand, N-heterocyclic carbene, benzimidazolium salt, catalyst, BRIDGED RESORCINARENES, EFFICIENT CATALYSTS, IMIDAZOLIUM SALTS, SYSTEMS, CYCLODEXTRINS, COMPLEXES, POLYETHYLENEIMINE, TETRAPHOSPHINE, AGGREGATION, CAVITAND
  • Acıbadem Mehmet Ali Aydınlar Üniversitesi Adresli: Hayır

Özet

Two mono-benzimidazolium salts of resorcinarene have been prepared and used as ligands in Suzuki-Miyaura cross-coupling reactions. They have been fully characterized by H-1 and C-13 NMR, MALDI, and FT-IR spectroscopic methods, and their structures were confirmed by X-ray diffraction analysis. These two new resorcinarene-based monobenzimidazolium salts showed good catalytic activity for coupling reactions in DMF. The highest conversion was achieved for arylation of 4-bromotoluene using the resorcinarenyl mono-dimethylbenzimidazolium salt.