Akademik Veri Yönetim Sistemi
35. ULUSAL KİMYA KONGRESİ, Diyarbakır, Türkiye, 9 - 12 Eylül 2024, ss.352, (Özet Bildiri)
How bisphthalonitriles spacer affects the properties of the corresponding cross-linked polymeric phthalocyanine materials
Haifa Ben Aziza1, Abdel Drissi El-Bouzaidi2, Atefeh Emami2, Fabienne Dumoulin2
Phthalocyanines are used as molecular or nanomaterials in several applications such as sensors [1], photodynamic therapy [2], or catalysis [3]. Beyond the need to design and prepare phthalocyanines with adequate properties depending on the targeting applications, it is useful to incorporate them into materials to further progress towards innovation and industrial translation.
In this work, we explore the formation of croSS-linked polymeric phthalocyanines prepared from bisphthalonitriles having different spacers [4], with various lengths and/or rigidity. The structural properties of the resulting polymeric materials will be commented relatively to the bisphthalonitriles’ space nature and geometry
Keywords: Polymeric phthalocyanines, structural properties
References
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[2] A. B. Sorokin, Phthalocyanine Metal Complexes in Catalysis, Chem. Rev. 2013, 113, 10, 8152–8191
[3] P.C. Lo, M.S. Rodríguez-Morgade, R. K. Pandey, D. K. P. Ng, T. Torres, F. Dumoulin, The unique features and promises of phthalocyanines as advanced photosensitizers for photodynamic therapy of cancer, Chem. Soc. Rev., 2020, 49, 1041-1056.
[4] M. Köç, Y. Zorlu, Ü. İşci, S. Berber, V. Ahsen, F. Dumoulin, A library of dimeric and trimeric phthalonitriles linked by a single aromatic ring: comparative structural and DFT investigations, CrystEngComm, 2016,18, 1416-1426.